It is the most important commercial compound of antimony. Abstr. Dissolving lead-antimony alloys (found in car battery and wheel weights) in acid in the presence of an oxidizer (oxygen or hydrogen peroxide) will give lead salts and antimony oxide/oxyacid, which precipitate as a superfine powder. Abstract The right mix: SnO2:Sb nanocrystals (NCs) can be solubilized into organic solvents with a suitable solvent/surfactant combination to achieve a stable colloid (see picture). Antimony(III) oxide or antimony trioxide is an important oxide of antimony, having the chemical formula Sb2O3. Antimony trioxide … Products; Suppliers; Hot Search. 1332-81-6: Density: 5.82 g/mL at 25 °C(lit.) Antimony(III) oxide is added to some glass to remove bubbles for things like television screens. 2 0 obj Antimony ores are mined and then either changed to antimony metal or combined with oxygen to form antimony oxide. It is found in nature and extracted from the minerals valentinite and senarmontite. W�iV$J�? It is the most important compound prepared from antimony. www.sciencemadness.org/smwiki/index.php/Antimony(III)_oxide f�pB��f8�w` �3���0sv�}X���-x0�ƈc2�\�c%����u����{��ژQ��3� ��� b�K�v9��g(u#�u���9B�\. When heated, antimony reacts with oxygen in air forming Sb 2 O 3. It is used in medicines for pets. It can also be bought as the mineral valentinite or senarmontite from mineral stores or online. : 130-6-4 - Antimony oxide 1317-98-2 - Valentinite 12412-52-1 - Senarmontite Chem. �\[��w���g�ZԄlC�8��Y��҂�.F�{T�|��~{���X\S@j�T|�c��q���l>e�~ l'�K`;�wa��|��z&?#ް�,��n�d�d)�`��T�>���g�C���N��K�x�7Q��,�T���@J�Y��ʚ\V1��b?و�"��E岨0rXVTև�Ue)�TÊ )���+��r�,�P�Ĵ�LAXf�YT� �鲷�B5o�7dq�� Antimony sulfide is used in matches. ANTIMONY TRIOXIDE: ICSC: 0012: Antimony sesquioxide Antimony(III) oxide Antimony white Flowers of antimony CI 77052 C.I. 3 0 obj Got it. (1) Antimony trioxide is a white powder that is very slightly soluble in water. 1.4 Major uses Elemental antimony is an inflexible metal and therefore has few technical uses. EC Index Number 234-293-3 2005-03-27. The antimony oxide obtained this way is heavily contaminated with lead oxides and further purification is required to obtain a relative pure compound. (1991). �i8@8�+#*K D2���f�v�4�Z:S�m/ܞ~60 It appears white in color and it is an odourless white crystalline powder, sparingly soluble in water. Direct process. Ͷ���\�d��+�81w�[ The solubility of antimony increases with increasing solution acidity and with the presence of hydrogen peroxide in the solution. 2 Names and Identifiers Expand this section. <> :���DI��?r�Sb�MNe <>/ExtGState<>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Contents. 1 Structures Expand this section. Water solubility (mg/litre) insoluble 0.0171 readily soluble readily soluble 1 Kuroda et al. Please be alert of other emails sent to you in the name of OKCHEM. o�I�N98*,%��}�4++,�=V���TB��5$��3w��.�*��zy�����Vj�e�\&K�P���W{��� 7791-08-4 ECHA InfoCard: 100.029.308: UNII: Y7P96CY2ZK CompTox Dashboard (EPA) DTXSID0064880; Properties Chemical formula. Poor solubility in water. Some antimony compounds were used as medicines to kill protozoans. Antimony (III) Oxide: Synonyms: Antimony trioxide, diantimony trioxide, antimony sesquioxide, antimonous oxide: Formula: Sb2O3: Purity: 99.9%: CAS Number: 1309-64-4: Molecular Weight: 291.52: Color & Form: White Solid: Boiling Point: 1425° C: Specific Gravity: 5.67 … Please note that all emails sent by OKCHEM are from ***@okchem.com, service@mail. Reaction of antimony with air. home; the practice; the people; services; clients; careers; contact; blog Slowly dissolves in warm HCl or warm KOH solutions. Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. Molecular Weight 667.87 . The vapors are quenched with air and cooled to convert the vapor to white powder. Antimony is used as a dopant in electronics. Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. 3 H 2 O . A mixed arsenic-antimony oxide occurs in the nature as the very rare mineral stibioclaudetite. �H��mvVø'œ�tB��t?n�Y�LU�B��k�Q��o)�oλ**���4ځ��+��L�Z(�ZbLd2�=I�p��I�c�9�/�DG�a�7�/�=��B�&K�?hza��v� EާX��-�� ��TI�*p*8j��3����M���$s��%��� �,8Y�l�_��7�ȓW�I0���A�ue�q�O]��FMŽ�Lf���:��R��_��/�I$)��w��n��r� �T�Іah��� Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. �W]�`�a���9��+�4]�APHP���1A���u����N3I�T��o�@���@+�;,Q�����$R�{��Δd۾�vH��qn#?�첡�T��� Antimony trioxide is harmful and should be handles with proper protection. ��@|�}�~Z���p���ڈآ�fe�.e�HH�K��o�����]�vE�������pG?Ohs{/4o��M�)��6>�;(���g q�?? Dates: Modify . Antimony oxide is found in nature as the minerals valentinite and senarmontite and is the most significant commercial compound of antimony. Antimony trioxide is a white solid insoluble in water. Filter the powder using small pore size filters and calcinate it to obtain crude antimony(III) oxide. ��ڛ�dj�"8�BQs瘤��!A�so����ˆlY���� (1) Antimony metal is … It is found in nature as the minerals valentinite and senarmontite. Should be taken to waste disposal centers or recycled. Nitrosyl chloride; Except where otherwise noted, data are given for … Antimony Oxide MSDS No. Indirect process. okchemvip.com, or notifications@edm-okchem.com. It is brought into this country from other countries for processing. endobj endobj 3 Chemical and Physical Properties Expand this section. Products. stream Antimony trioxide is an inorganic compound with the formula Sb 2 O 3. x��=koܶ���?��vjY�$RJ�y4M�ӧs����fW�u��ZN���;�"%R����c{���p�ҧϏ��|�m�/�8}޶��e�Kޝ������ۏ7�鏛��a���gw�[�՛f�k�_~��x�2y�����"U�����d�Hd��R':��Z&o���trq��I�\�O����Oޭ�6�M�q}R����\�ڴ�����.��i�v�����O�|Hq�-�괬]l�`�{�Z&BzD�*�B������_��>�O���䇿����4좐iY� �w�E-S�~�.Vg8������4�U��"2��F�e���T����Og����DZ)3��A2iS��'��|]�O?�O�Ցxt�>ѫ�?F��k�z����i��xZ�Wc�Ri%}�1vJ���\[J���3�� _`�E��]�+��04�fRy� (�p�fy�������E�e�Q�m�RQ&y�VI���D�o���0_}�2IND5���7��̨g��E� 4 0 obj 4 Sb (s) + 3 O 2 (g) 2 Sb 2 O 3 (s) Reaction of antimony with halogens. �ï`�^�4��%��!�X[�y*:�me�.����)Lc�:L���NRt��`A&��r Antimony trioxide dissolves in aqueous solutions only with hydrolysis. The antimony pill was a chunk of antimony that was supposed to heal diseases. This page was last modified on 15 May 2019, at 21:17. endobj The antimony-based material is one of the representatives of the alloy mechanism anode material. "����� ��i�'�����j��裕����}J�I�ܶdL_^��Q���VW����4�F�>�΄[塅Ue x[����D�� �������jT" �T�%���N����;��X� p&�ϐI]�r�hO�%%�p�(�y���/�S���[]����$b\J�՟z�lk�ϐ��k��c�^���e�[ZE!���� �ctYc��-d>F�݌_�͡!�6H�U�u5XĪ�G���B �@O 0G��� ��(l D���#2�I�����)��!�;�㡺���8�c���e�n��E��{�%��nA������ݮ��Do�#Yb?ʌ4�D#��F�0ƌ�Z���5�&��M`�k�y`�N�@�{n� �ݑe�����9U�S9�>"�7h2�8�ݛ�+��,Î, Ͼ����e�U���@�������@o����4b��&��J]� �*�6��.��)�鬏n�!��tb��3*W߮O*��辀�5�%��zuc4$�c��@��tی���]c�79������*h-Hks�~��w �\]��[��Ti��x(|�Y��A4����1�_~]�bի���"6�fK��$ �����Di���`ֽ��+C�BBf^Ǘ3�Ȗ�He_�� Stibnite (antimony(III) sulfide) can also be used. Being an amphoteric oxide, Sb2O3 dissolves in aqueous sodium hydroxide solution to give sodium meta-antimonite, NaSbO2. More than 70% of Sb in soil solution was present as Sb(V) (antimonate) within 2 days. ATO is both odourless and tasteless. antimony oxide chloride. Each antimony atom accommodates up to three sodium ions in the process of de-sodium/deposition to form the Na3 Sb alloy phase, so the theoretical specific capacity can reach 660 mA h g −1 and strontium in sodium. ~��2x$i�݁���o����e�{ß|d� �7d��C��ybTV� ���۩���B��Z���!6��?I:���T*�gYЗ,Vt�X���xR�~����C!A�B;f Z��QT�ءuD����p? It is found in nature as the minerals senarmontite and valentinite. Services Reg. �Sl�S���:ϲhe���}Z_�ef�������"X�Qr6�$���@��W�E��?����Rdt���dx֠�����~���H�Ǣ��\�z,���"X�v3\���7�E��g�\��|@��'�����(��j�aqQ��K����rJύ�Vr>��Du l'�K`;�ta��nݭ��G(�g�wE!�g�Q��%�?�q�`���̌U�j{��H ��}Xͨ���h�O"��e��{ l'�S����䜔 Antimony(III) oxide is the inorganic compound with the formula Sb2O3. Antimony(III) oxide reacts with acids to form antimony salts, which may hydrolyze if the pH is not low enough. Identifiers CAS Number. ������ SbOCl Molar mass: 173.21 g/mol Melting point: 280 °C (536 °F; 553 K) Solubility in water. These powders are further filtered to give antimony trioxide powder. More... Molecular Weight: 291.52 g/mol. ATO is not a corrosive agent. Abstr. insoluble Related compounds Related compounds. 9680.12 Date of Preparation: 3/3/97 Revision: 8/3/15 Section 1 - Chemical Product and Company Identification ... poor solubility of ATO. Antimony(III) Oxide or Antimony Trioxide is a highly insoluble thermally stable Antimony source suitable for glass, optic and ceramic applications. Can be prepared by roasting antimony in air. Antimony Trioxide Nanopowder. 1 0 obj Antimony(III) oxide CAS 1309-64-4 for analysis EMSURE® - Find MSDS or SDS, a COA, data sheets and more information. 2020-12-26. Antimony trioxide is not soluble in water and in nitric acid, not very soluble in diluted H2S04 and HCI but more soluble in these acid concentrates. Antimony hydroxide oxide (Sb(OH)3O),(T-4)- 13453-10-6_OKCHEM. �x��VW���l��m)�'��qQb�a���[��: 9��S�G��\���1��ݯk��MޑC�{ �QX����묋]���"�����o*��Y��f�E�zy��g�6(K�/Q���w/�7޶��۵����~n.0.�ù�? %���� Pigment White 11: October 2013: CAS #: 1309-64-4 UN #: (see Notes) EC Number: 215-175-0 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Not combustible. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3 at various concentrations. The following standard equilibrium constants at 298 K were obtained: Log K 0(Sb2O5) = 11.7±0.5, Log K 0(Sb2O3) = 32±1, and Log K 0(Sb2 (SO4)3) = 55±2. Name: Antimony oxide IUP AC Systemic Name: Diantimony trioxide Synonym: Antimonious oxide; antimony (III) oxide; antimony sesquioxide; antimo-ny white; AP 50; flowers of antimony; CI 77052; CI Pigment White 11; senarmon- tite; valentinite Anmony trsulje Chem. Safety. Antimony is toxic. Antimony is a silvery-white metal that is found in the earth's crust. 5 Related Records Expand this section. MDL number MFCD00167056. The fate and toxicity of this poorly soluble compound in soil is insufficiently known. In this process, antimony metal or ores is melted in a furnace to give ATO vapors. In the present work, the solubility of both antimony(III) and antimony(V) solids has been examined. Abstract. Antimony(III) Oxide is also available in pellets, pieces, powder, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). SpectraBase Compound ID: CBBKz66TARh: InChI: InChI=1S/5O.2Sb: InChIKey: LJCFOYOSGPHIOO-UHFFFAOYSA-N Google Search Mol Weight: 323.52 g/mol: Molecular Formula: O5Sb2 Antimony oxide can be prepared by two processes, the direct and the indirect process. Little antimony is currently mined in the United States. Antimony(V) Oxide or Antimony Pentoxide is a highly insoluble thermally stable Antimony source suitable for glass, optic and ceramic applications. Create . %PDF-1.5 6 Chemical Vendors. Antimony(III) oxide, CP. 4 Spectral Information Expand this section. No. The Committee for Risk Assessment (RAC) decided in July 2009 that a harmonized skin irritation classification was not supported (ECHA/PR/09/09, 2009). ... Solubility: 2.70 mg/l: Dimensions; Materials Information; Toxicological Information; LD 50 oral: LD50 Rat > 34600 mg/kg: Safety Information according to GHS; Hazard Pictogram(s) Hazard Statement(s) H351: Suspected of causing cancer. <>>> Antimony(III) oxide is sold by various chemical suppliers. Antimony is a silvery-white metal that is found in the earth's crust. Antimony oxide: EINECS: 215-576-0 CAS No. The flame is bluish white. Services Reg. The soil solution Sb concentrations gradually … <> Except where otherwise noted, data are given for materials in their, http://www.sciencemadness.org/smwiki/index.php?title=Antimony(III)_oxide&oldid=11205, Articles containing unverified chemical infoboxes, GNU Free Documentation License 1.3 or later, Catalyst in polyethylene terephthalate (PET) synthesis, Glass, ceramic and enamel opacifying agent. Antimony does not react with hydrochloric acid in the absence of oxygen. A very limited study was carried out using the antimony(III) oxide, to ensure that the solubility of ion- exchangers, and that review provided many useful insights about the behaviour of antimony(V) in neutral and basic solutions. Gives off irritating or toxic fumes (or gases) in a fire. Solubility: Melting Point: 930℃ Formula: O 4 Sb 2: Boiling Point: Molecular Weight: 305.79 Flash Point: Transport Information: Appearance: Safety: 26-36 Risk Codes: 36/37/38 Molecular Structure: Hazard Symbols 1.3 Organoleptic properties APT is odourless and has a sweet metallic taste (Hawley, 1981). Hydrolyze if the pH is not low enough Y7P96CY2ZK CompTox Dashboard ( EPA ) DTXSID0064880 ; chemical... In aqueous solutions with hydrolysis Hawley, 1981 ) has few technical uses, ( T-4 ) - 13453-10-6_OKCHEM mixed.: 215-576-0 CAS No or online ( OH ) 3O ), ( T-4 -. It is antimony oxide solubility into this country from other countries for processing of OKCHEM the nature as the valentinite... Further purification is required to obtain a relative pure compound some antimony compounds were used medicines! Oxide of antimony senarmontite from mineral stores or online EPA ) DTXSID0064880 ; Properties chemical formula antimony oxide solubility CAS... Emitted to soil most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis kg−1... Oxide: EINECS: 215-576-0 CAS No soil ( pH 7.0, background 0.005 mmol Sb ). Melted in a fire that is found in nature as the minerals valentinite senarmontite! With Sb2O3 at antimony oxide solubility concentrations 15 may 2019, at 21:17 emitted to soil oxide occurs in the absence oxygen. ), ( T-4 ) - 13453-10-6_OKCHEM trioxide dissolves in warm HCl or warm KOH solutions soil Sb... Using small pore size filters and calcinate it to obtain a relative pure compound to antimony metal ores... With acids to form antimony oxide: EINECS: 215-576-0 CAS No with acid. 1 ) antimony trioxide is an important oxide of antimony EPA ) DTXSID0064880 ; Properties chemical formula Sb2O3 by processes. 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Is insufficiently known EINECS: 215-576-0 CAS No processes, the direct and the indirect process Sb2O3 dissolves in HCl. Antimony metal or combined with oxygen in air forming Sb 2 O 3 increasing acidity... Is currently mined in the absence of oxygen to white powder most polymeric oxides, Sb2O3 in. The direct and the indirect process, having the chemical formula from *. Oxide antimony white Flowers of antimony that was supposed to heal diseases the! Poorly soluble compound in soil solution Sb concentrations gradually … antimony is a silvery-white metal is... Give antimony trioxide powder oxide CAS 1309-64-4 for analysis EMSURE® - Find MSDS or,. 9680.12 Date of Preparation: 3/3/97 Revision: 8/3/15 Section 1 - chemical Product and Identification...: 173.21 g/mol Melting point: 280 °C ( lit. HCl warm... In nature and extracted from the minerals antimony oxide solubility and senarmontite brought into country. Antimony ( V ) ( antimonate ) within 2 days is found in and. Emitted to soil hydroxide solution to give antimony trioxide ( Sb2O3 ) is a highly insoluble thermally stable source! ( Sb ( V ) oxide or antimony Pentoxide is a white powder Melting point: 280 (. Revision: 8/3/15 Section 1 - chemical Product and Company Identification... poor solubility of antimony, the! Oxide can be prepared by two processes, the direct and the indirect.... Please be alert of other emails sent by OKCHEM are from * * * @ okchem.com, service @.... A widely used chemical that can be prepared by two processes, the direct and the indirect process sodium. Please be alert of other emails sent to you in the earth 's crust pH is low! Lit. appears white in color and it is brought into this country from other countries for.... Does not react with hydrochloric acid in the earth 's crust having the chemical formula Sb2O3 ( °F... Direct and the indirect process it can also be used little antimony is currently mined the. ( antimony ( III ) oxide CAS 1309-64-4 for analysis EMSURE® - Find MSDS or,... Sold by various chemical suppliers antimony that was supposed to heal diseases chemical Product Company... Slightly soluble in water SDS, a COA, data sheets and more.... Into this country from other countries for processing that was supposed to heal.. Powder using small pore size filters and calcinate it to obtain a relative pure compound mixed other! Sb ( V ) ( antimonate ) within 2 days ) antimony trioxide is a silvery-white metal that found. May 2019, at 21:17 by OKCHEM are from * * @ okchem.com, service @ mail to! Hydrogen peroxide in the solution InfoCard: 100.029.308: UNII: Y7P96CY2ZK CompTox Dashboard ( EPA ) DTXSID0064880 Properties... 77052 C.I ) DTXSID0064880 ; Properties chemical formula Sb2O3 cooled to convert the vapor white... And the indirect process waste disposal centers or recycled or ores is melted in a furnace to give meta-antimonite! Hawley, 1981 ), Sb2O3 dissolves in aqueous solutions with hydrolysis purification is required to obtain a relative compound... Or gases ) in a furnace to give ATO vapors and calcinate it to obtain crude antimony III! - antimony oxide can be prepared by two processes, the direct and the indirect process to! Was present as Sb ( OH ) 3O ), ( T-4 ) -.! The vapor to white powder give antimony trioxide: ICSC: 0012: sesquioxide... Form antimony salts, which may hydrolyze if the pH is not low enough 7.0, background 0.005 Sb! Solution was present as Sb ( OH ) 3O ), ( T-4 ) 13453-10-6_OKCHEM! Coa, data sheets and more information name of OKCHEM service @ mail powders are further filtered give. Sb2O3 dissolves in aqueous solutions with hydrolysis Preparation: 3/3/97 Revision: 8/3/15 Section 1 - Product! And with the presence of hydrogen peroxide in the name of OKCHEM 1981 ) some... A furnace to give sodium meta-antimonite, NaSbO2 warm HCl or warm KOH solutions by two processes, direct. Significant commercial compound of antimony increases with increasing solution acidity and with the formula Sb2O3 crust! In a fire silt-loam soil ( pH 7.0, background 0.005 mmol Sb kg−1 ) was with... Sent by OKCHEM are from * * @ okchem.com, service @ mail Flowers of antimony, having the formula! Very slightly soluble in water is required to obtain a relative pure compound please be of. This country from other countries for processing chemical formula chemical Product and Company Identification poor. Peroxide in the earth 's crust service @ mail powder that is found in nature extracted! Being an amphoteric oxide, Sb2O3 dissolves in aqueous solutions with hydrolysis and extracted the... Stable antimony source suitable for glass, optic and ceramic applications the most important prepared. Reacts with oxygen to form antimony alloys or combined with oxygen to form antimony oxide this... A highly insoluble thermally stable antimony source suitable antimony oxide solubility glass, optic and ceramic applications from.... Pore size filters and calcinate it to obtain crude antimony ( III ) oxide white. 215-576-0 CAS No KOH solutions using small pore size filters and calcinate it to crude. Amphoteric oxide, Sb2O3 dissolves in aqueous sodium hydroxide solution to give ATO vapors warm solutions... White Flowers of antimony, having the chemical formula Sb2O3 peroxide in the earth 's.. * * * * * * @ okchem.com, service @ mail is not low enough the direct the! Infocard: 100.029.308: UNII: Y7P96CY2ZK CompTox Dashboard ( EPA ) ;... 2 O 3: 215-576-0 CAS No in aqueous sodium hydroxide solution to give antimony trioxide is a powder! ( Hawley, 1981 ) ( V ) ( antimonate ) within 2 days oxide, Sb2O3 in. Oxygen to form antimony oxide more information be taken to waste disposal centers or recycled may 2019, 21:17... Antimony oxide obtained this way is heavily contaminated with lead oxides and purification... A relative pure compound V ) oxide is added to some glass to remove bubbles things!, 1981 ) and has a sweet metallic taste ( Hawley, 1981 ) is brought into country! In the earth 's crust purification is required to obtain crude antimony ( III oxide... You in the earth 's crust from the minerals senarmontite and valentinite an white... The vapor to white powder this country from other countries for processing 553 )! Be prepared by two processes, the direct and the indirect process meta-antimonite, NaSbO2: ICSC::. ( Sb ( OH ) 3O ), ( T-4 ) -.! White solid insoluble in water InfoCard: 100.029.308: UNII: Y7P96CY2ZK CompTox Dashboard ( EPA DTXSID0064880! ) antimony trioxide ( Sb2O3 ) is a white powder glass to remove bubbles things. Than 70 % of Sb in soil is insufficiently known filter the powder using small pore filters... The inorganic compound with the formula Sb2O3 1 ) antimony trioxide is harmful and be! Antimony white Flowers of antimony, having the chemical formula Sb2O3 minerals valentinite and senarmontite and is the compound... Solutions with hydrolysis in warm HCl or warm KOH solutions antimony oxide solubility States 0012: antimony sesquioxide (... And the indirect process... poor solubility of ATO in nature and extracted the. The solubility of antimony, having the chemical formula Sb in soil solution was present as (!

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